Selectively Patterning Polymer Opal Films via Microimprint Lithography

Abstract

Electrically tuned photonic crystals are produced by applying fields across shear-assembled elastomeric polymer opal thin films. At increasing voltages, the polymer opal films stretch biaxially under Maxwell stress, deforming the nanostructure and producing marked color changes. This quadratic electro-optic tuning of the photonic bandgap is repeatable over many cycles, switches within 100 ms, and bridges the gap between electro-active materials and photonic crystals.

Publication
Appl Phys Lett 2012, 100 (10), 101902
Qibin Zhao
Qibin Zhao
Associate Professor

My research focuses on soft functional materials in which mesoscale structure controls optical and physical properties. I have worked extensively on colloidal and particle-assembled photonic materials, developing scalable processing methods to organize soft particulate systems into structurally coloured films and coatings. A central theme of my work is how external mechanical fields, such as shear, bending, stretching, and cyclic deformation, can drive microstructural ordering, lattice transitions, and structure-dependent optical responses. More broadly, I am interested in programmable soft photonic materials and functional coatings, where colloidal assembly, deformation processing, and soft-matter physics can be used to create adaptive optical, thermal, sensing, or mechanically encoded material functions.